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Preheat
oven to 350 degrees. Generously butter a 9-by-5-inch loaf pan; set
aside. Whisk together the cake flour, baking powder, and salt; set
aside.
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In
the bowl of an electric mixer fitted with the paddle attachment, beat
the butter and sugar until light and fluffy, about 5 minutes. Add eggs, one at a time, beating until combined after each addition and scraping down the sides of the bowl as needed. Mix in vanilla. Add flour mixture in 2 batches, alternating with the buttermilk and beginning and ending with the flour. Set aside 1/3 of the batter.
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In
a bowl, mix cocoa and 1/4 cup plus 2 tablespoons boiling water with a
rubber spatula until smooth. Add the cocoa mixture to the reserved cake
batter; stir until well combined.
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Spoon batters into the prepared pan in 2 layers, alternating spoonfuls of vanilla
and chocolate to simulate a checkerboard. To create marbling, run a
table knife (or wooden skewer) through the batters in a swirling motion.
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Bake,
rotating the pan halfway through, until a cake tester comes out clean,
40 to 50 minutes. Transfer pan to a rack to cool 10 minutes. Turn out
cake from pan and cool completely on the rack. Cake can be kept in an
airtight container at room temperature up to 3 days.
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