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Make
the cake: Preheat oven to 325 degrees. Butter a 14-cup Bundt pan. Whisk
flour, cocoa, baking soda, and salt in a large bowl. Mix milk and sour
cream in a small bowl.
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Cream
butter and sugar with a mixer until light and fluffy. Beat in eggs, 1
at a time, then vanilla. Reduce mixer speed to low, and add flour
mixture, alternating with milk mixture, ending with flour. Fold in
walnuts, if using. Spoon batter into pan. Bake until a tester inserted
in center comes out clean, 55 to 60 minutes. Let cool in pan on a wire
rack. Invert cake. (Cake will keep for up to 1 day.)
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Make
the glaze: Place chocolate in a bowl. Heat cream in a small saucepan
until simmering, then pour over chocolate. Let stand for 2 minutes. Add
butter and Cognac or rum, if using, and mix until smooth. Let stand,
stirring occasionally, until slightly thickened. Pour glaze over cooled
cake. Slice, and serve with tangerine segments.
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